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Abstract
Thermophilic (high temperature requiring)
sulphate-reducing bacteria (tSRB) are responsible for both corrosion of the oil
production facilities and souring of the produced oil. During oil recovery,
a range of chemicals is injected into oil reservoirs for various operational
reasons. Such chemicals may be designed to inhibit microbial growth, or to
specifically inhibit general corrosion. Other chemicals such as scale
inhibitors, oxygen scavengers, H2S scavengers and surfactants may
also be injected. To date, there is little published data on the effect of
any of these chemicals on the micro-flora that is known to exist in the oil
formation.
The effect on sulphide production using a tSRB isolated from an
oil bearing chalk formation was monitored in the presence of rock surfaces and
individual chemicals. The presence of a surface increased sulphide
production whilst oilfield chemicals produced a variety of responses, from
complete inhibition to significant enhancement of sulphide
production. Differences were observed within the various classes of
treatment chemicals. Some molecules appeared to break down more easily than
others under reservoir conditions and thus served to stimulate sulphide
production. The data obtained will help to manage oil reservoirs in a more
cost-effective and environmentally friendly manner, minimising both sulphide
production and microbial corrosion by determining appropriate chemical selection
and dosing regimes.
Venue: Second Arabian Corrosion
Conference
Authors: P F
Sanders, H M Lappin-Scott, C J Bass
Date: October 1996 |